getting all the gold out of your concentrates (2024)

Every placer miner has to deal with it in one form or another, and some locations have it far worse than others, but nearly every placer has at least some of it: black sand. It collects in our concentrates and gets in the way of recovering our fine gold. Some prospectors worry about getting every speck of gold and save it in buckets until they have tons – others take all the gold they can conveniently remove and then toss out the rest. So what is this mysterious stuff and what should we do about it? Lets take a look at black sands and the best ways to extract all the gold that is reasonable to get, and our options for recovering that gold.

The sand, rocks and gravels in the placer deposits we work have a density of about 2.5 to 3. Gold on the other hand, has a density of 19.3 when pure. That difference is what makes all the gravity methods of capturing gold work – whether it’s a simple pan, or a sluice box, dredge, dry washer, table or jig, that big difference in density is what makes working with placers pretty easy. However, these gravity-based methods are not just specific to gold – they capture all the heavy materials in the placer and concentrate them, including black sands. The frustrating thing about black sand is that while it is relatively easy to separate the normal sand and gravel from the gold, it much more difficult to separate the small sized gold from the black sand and other concentrates. There are many methods to accomplish this job – some a lot more efficient than others.

Black sands are heavy, which is why they collect in your pan, dry washer or sluice. They have density of about 5, meaning that those black particles are about 5 times heavier than water. Perhaps the first question about black sands is along the line of “what is this stuff?” Normally, most of black sand is made up of two crystalline oxides of iron:magnetite and hematite. Hematite has a density of 5.3, and magnetite a density of 5.2. Its not surprising that two iron minerals dominate the concentrates, as iron is the fourth most common element in the earth’s crust. Both are found in a number of different types of rocks, and when these two materials occur in great enough concentrations, they are important iron ores. When rocks containing these minerals is weathered and eroded, they collect in streams and drainages. Chemically, magnetite has a formula Fe3O4. Its crystalline structure places it in the spinel family of minerals. It melts at 1538 C and has a density of 5.2. It’s structure makes it highly magnetic. Hematite is not so chemically resistant as Magnetite, and its chemical formula is Fe2O3. The little known secret about hematite is that it is actually very slightly magnetic. Nothing like magnetite mind you, and most magnets will not lift it, but it can be picked up with certain extremely strong rare earth type magnets and we will talk more about that important fact shortly. getting all the gold out of your concentrates (1)

In addition to magnetite and hematite, black sands may also contain small amounts of a lot of different heavy minerals depending on the rock types in which you are working. Heavy concentrates may or may not contain at least some of the following: chromite (an ore of chromium), Diamonds, platinum, gold bearing amalgam (lost by early day miners), lead (from fishing weights and bullets), floured mercury, cinnabar (a natural mercury ore),sheelite (tungsten ore), zircon (a rare gem with a density of 4.7), garnets, pyrite and barite. The proportions that you may find of these minerals or man-made products depend on the specific location where you are prospecting. Some of these things, like diamonds, platinum and amalgam, are valuable in their own right. Mercury and amalgam may contaminate the gold you recover in your sluice box.

The amount of black sand and other heavy minerals, which you find associated with your placer gold, varies a lot – there is not a simple direct correlation. There are places that are loaded with black sand but have no gold. Conversely, there are also places that have good quantities of gold but very little black sand.

It seems like at least a little black sand is found practically everywhere, so perhaps the next question is “where is all this black sand coming from?” As I noted iron is the fourth most common element in the earth’s crust, so some iron-bearing minerals are found in most rock types. They are especially common in metamorphic and igneous rocks. Since gold deposits are often associated with igneous and metamorphic rocks, it’s easy to see why we nearly always find at least some black sands in our placers. So now that we know a bit about this stuff and where it comes from, what are we supposed to do to get the gold out of it?

First, many new prospectors, believing that it somehow contains large quantities of “hidden” precious metals, find black sand mysterious and incomprehensible. Often this leads to the promotion of expensive and highly questionable treatments to “unlock” the “invisible” values of black sand – including “special” assays, strange leaching techniques, and “magic” fluxes. The truth is that most of the values in black sands are simple free gold particles, which are recoverable by standard gravity recovery methods. Any values truly locked into the black sand, surrounded by minerals such as magnetite so that it cannot be recovered by normal gravity separation systems, are typically very small. The amount of any truly “locked in” gold can be scientifically determined by very meticulously recovering all the free gold possible from a sample of black sand, making sure to carefully examine it under 10x magnification to see that all the free gold has been removed, and then take that clean black sand and run a standard fire assay on it. Do an assay before you invest money in any expensive treatments, because in nearly all cases, this assay will show it is not economically worthwhile to pursue any further treatment of the black sands, especially for the small operator.

getting all the gold out of your concentrates (2)

The answer as to how to best deal with black sand depends on how much you are generating. If you are an individual prospector who dredges or dry washes during weekends or while on vacation, you might generate 20 to 200 pounds per year. If you just snipe with a pan or use a hand operated sluice box, the amounts will be even less. On the other hand, if you are a large commercial operator, you may produce tons of black sand, and the use of more sophisticated equipment such as shaker tables will be justified. Lets take a look at both possibilities:

Dealing with Small Quantities of Black Sands: This is the category into which most prospectors and weekend or seasonal miners fall – including me. I normally spend a week or two per year dredging, and combined with my other prospecting, I generate something around 20 to 40 pounds per year of black sands that need to be processed. Here are the techniques I use to go from concentrates fresh out of the sluice box, all the way to clean gold.

At the end of each dredging day, I clean up the front section of my 3 stage sluice box. About every other day I clean out rear top section, and about once per week I clean out the undercurrent section of the sluice box. Many new miners, worrying about loss of gold, clean up too often and this takes away from the time they could be dredging and finding more gold. Sluice boxes on newer dredges are well designed, and if your sluice is set up so that the gravel is not accumulating so much that it buries the rifles nor running so fast that it sweeps the rifles and carpet clean, then once a day clean up is all you should need on most store bought dredges. When operating properly, your sluice will have about one inch of carpet showing between the gravel of the middle riffle of the sluice and the one below it.

. After dredging all day, I empty off my sluice into a large plastic wash tub. I then screen those concentrates using a quarter inch screen to get rid of the small rocks. Any gold that fails to go through a quarter inch screen is a nice nugget. After a quick sort to find any coarse nuggets, the reject rocks and pebbles are discarded. The next step is to pan through the remaining concentrates. The point of this step is to remove the light sands which are in those concentrates. Once I have panned through the fines so that the lighter sand is removed, and I take out any pickers, flakes and small nuggets large enough to be worth removing by hand. After all these larger pieces have been removed, all that remains is a small amount of black sand, which contains all the fine sized gold and other heavy mineral concentrates. I then put these concentrates into a container – lately I am using the new plastic coffee cans. Don’t use metal cans to store wet black sand as the cans rust and it will cause the black sand will harden up into a solid mass. I save and accumulate this fine black sand and gold concentrate all season, waiting to process it all at once at the end of the year. getting all the gold out of your concentrates (3) Dry washing concentrates are processed in a similar manner, depending on where I am camping. In locations where it is easier to haul all the concentrates around than it is to haul all the water needed to process them, I sometimes simply take all my dry wash concentrates home and process them in a tub at the house. The clean black sand and fine gold is added to the black sand fines obtained by dredging, sniping, or sluicing for final processing at the end of the prospecting season.

At the end of the prospecting year (which for me is late October or early November), I have accumulated something between 20 and 40 pounds of black sand concentrate. In my final clean up, I use a blue bowl hooked up to my garden hose. Careful screening is the key to success with the blue bowl. First I screen the concentrates with a 30 mesh screen. I pan down the coarse matter which is larger than 30 mesh, until there is only a few cups of this material. The minus 30 mesh material is then processed in the blue bowl. Processing this material in the blue bowl is not fast, but it does work. You can relax while you are doing it as not much attention is required once it is set up. I will add about a cup of black sand, then run the bowl for a few minutes, shut down the water flow and add another cup or so, etc. until I have gone through the entire amount of –30 mesh black sand. I do not

take the material down to pure gold in the blue bowl, but it does remove the majority of the black sand. At this point, you are left with a cup or so of coarse material you panned down, and about 2 cups of fine gold and black sand. Recommended
Metal Detectors
For Gold Prospecting:
The next step requires a very strong magnet – you will need one of the new rare earth super magnets, and a good sized one with about 50 pounds or more of pull. Now your normal horseshoe magnet made of iron alloys simply will not do for this. The magnets sold by the most of the major prospecting shops to separate out black sands will not do. Those old style magnets will pick up magnetite, but not hematite. The new powerful rare earth super magnets are necessary because they will pick up the hematite, which is only very slightly magnetic. The old magnets will pick up around half of the black sand, but the super magnets will remove more than 95% of it – and that makes a big difference! These magnets are so strong that you need to be careful – you can get your fingers pinched and smacked as these super powerful magnets attract steel objects from surprising distances and with great speed. getting all the gold out of your concentrates (4) Put the concentrates in a plastic pan with about an inch or two of water – and spread them out into a thin, even layer. Carefully pass the magnet over the black sand from about a half inch above the black sand concentrates. On this first pass, do not touch or stir the concentrates with the magnet. The trick is to make the magnetite and hematite jump up through the water to the magnet leaving the gold behind. Remove the black sand that sticks to the magnet and repeat. Eventually, when nearly all the magnetic minerals are removed, you can stir the magnet through the remaining sand in order to pick up as much of the material as possible. This is the part of the process where you need to examine the material on the magnet very closely as a few particles of gold may be attached to magnetite and stick to the magnet. Repeat the process until no more magnetic minerals can be removed. You can examine the material you removed in the last part of the process with a magnifying glass to see how well you did. Remember a few tiny specs of gold may only be less than a dime’s worth, so there is no great need to worry too much about them. This process is done separately for both the 30+ mesh size and the –30 mesh size. The next step is to dry both fractions separately. . After removal of all magnetic minerals, only a few items normally remain. Gold, a few bits of lead, a garnet crystal or two, etc. , may remain in the 30+ mesh size. This fraction is easily sorted with your fingers when dry on a white sheet of paper. The trash is discarded and the gold (plus any other valuables like platinum pieces) are saved. The smaller fraction may have some non-magnetic black sand (commonly Chromite in many parts of California) and some grey-white heavy sand of a very fine size (commonly Zircon). When dry these can also be separated on a white sheet of paper – I normally use two sheets and with a little careful blowing on these smaller final concentrates. With care and a little effort, using this technique you can produce a clean gold product ready for sale or shipment to a refiner. By the way, that 20 to 40 pounds of black sand typically yields around 2 or 3 pennyweight of fine gold, an amount well worth my time and effort.

There are of course, a number of ways to go about doing this final cleanup. Some folks use mercury to get the small gold. I have done this in the past, but with the advent of the super magnet and the method outlined above, in my opinion, mercury is simply no longer necessary for the individual prospector. I like to stay away from the use of mercury, because the regulatory agencies go so crazy about it. All in all, it is faster not to use it. There are spiral panning wheels, micro sluices, tables and other devices for final clean up, they can do the job and all have their proponents, but I use a blue bowl, mostly because it is cheap and it works.

Sometimes (actually fairly often) my gold needs to be treated to remove mercury stains that either happen in the river or during recovery and processing. I prefer to use nitric acid for this, but some guys also remove mercury by heating. Mercury vapors are toxic, so do this outside and be careful – also be sure all the lead has been removed before heating, or you will have to use nitric acid to separate the melted lead from the gold.

Dealing with Larger Quantities of Black Sands from Commercial Operations: Even small commercial operations may generate more than 50 pounds of black sand per day, and processing equipment beyond the scope of the individual prospector is normally well justified. These operators commonly make use of shaking tables, large spiral wheels, mercury amalgamation and other commercial equipment to handle these larger volumes of black sand concentrates.

It is always important for the commercial operator to keep close tabs on his recovery equipment and do regular testing to make sure it is working properly. If this is not done, the operator may well be loosing significant fine gold. During the early 1980’s I had the privilege to inspect and evaluate the operations of St. Joe Minerals’ bucket line dredge operation at the Yuba Goldfields near Yuba City, California. At the time, they delivered their entire finished black sand product to the property owner after they had extracted all the gold that they believed was present in the material. It turned out that they were not keeping good controls on their processing. The property owner simply had one of his employees re-run the black sand over a finishing style shaker table, and he recovered additional gold, in the amount of about 3 ounces per day.

Large operators who generate many tons of black sand each year may wish to consider additional steps beyond tables or spiral wheels such as reprocessing after crushing the black sands or leach extraction by cyanide. However, these options should be considered only after assaying the finished tailing material to see if cost and effort of any additional processing is justified. With the continued regulatory concern over mercury, it has lost much of its traditional place as a method of recovering fine gold, but it is still used, especially in less economically developed countries. For commercial operators in the US, mercury can be a significant environmental liability, as even comparatively small spills may be quite expensive to clean up.

Mercury is still used by some small prospectors, and if you do choose to use it be sure to take all necessary precautions. The use of mercury potentially involves some inherent risk to your health if not done properly. In the final step, the mercury is distilled in a retort in order to recover all the dissolved or amalgamated metals. The fumes are toxic, and mercury chemicals can be absorbed through the skin. Once Mercury is absorbed into the body, it is retained for a long period of time and it attacks the central nervous system. I used to use mercury to recover my fine gold, but the advent of the rare earth super magnet has convinced me its unnecessary for my efforts to separate my beautiful placer gold from those nasty black sands.

For reference, see my page on using Mercury Amalgamation to Recover Gold.

.

Want to know a little bit more about this crazyprospector guy? Well, here's a little bit more about me, and how I got into prospecting: Chris'Prospecting Story Interestedin seeing more gold? Here are some interesting photos of beautiful Gold Nuggets I'm the associate editor for a well known Gold Mining Magazine - so check out their website for more information and my latest articles.

I'm an enthusiast with extensive knowledge in placer mining, particularly in dealing with the challenge of black sand and extracting gold from it. My expertise comes from practical experience and a deep understanding of the various methods and techniques involved. Now, let's delve into the concepts mentioned in the article.

  1. Density Difference:

    • Placer deposits contain sand, rocks, and gravels with a density of about 2.5 to 3. Gold, with a density of 19.3, allows gravity-based methods to capture it effectively.
    • Black sands, having a density of about 5, are composed mainly of magnetite and hematite, both iron oxides.
  2. Composition of Black Sands:

    • Magnetite (Fe3O4) and hematite (Fe2O3) are the primary components of black sands, with magnetite being highly magnetic.
    • Besides iron oxides, black sands may also contain various heavy minerals such as chromite, diamonds, platinum, lead, mercury, tungsten ore, zircon, garnets, pyrite, and barite.
  3. Origin of Black Sands:

    • Black sands are common in placer deposits due to the prevalence of iron-bearing minerals, especially in metamorphic and igneous rocks.
    • Gold deposits, often associated with these rock types, lead to the presence of black sands in placers.
  4. Dealing with Black Sands - Small Quantities:

    • Techniques for processing small quantities involve cleaning the sluice box, screening concentrates, panning, and using a blue bowl with a rare earth super magnet for final cleanup.
    • The goal is to separate gold from black sands efficiently without resorting to expensive or unnecessary treatments.
  5. Dealing with Black Sands - Larger Quantities (Commercial Operations):

    • Commercial operations handling larger volumes of black sands may use shaking tables, large spiral wheels, mercury amalgamation, or other specialized equipment.
    • Close monitoring and regular testing of recovery equipment are essential to avoid losing significant fine gold.
  6. Environmental Considerations:

    • The use of mercury, once a common method for recovering fine gold, has environmental concerns and regulatory issues. Some small prospectors may still use it, but precautions are necessary.
    • The advent of rare earth super magnets has provided an alternative to mercury, reducing environmental risks.
  7. Final Cleanup and Recovery:

    • The final steps involve careful separation of magnetic minerals using a strong magnet, followed by drying and sorting. Various techniques like spiral panning wheels or tables can be employed for final cleanup.

This summary provides an overview of the key concepts related to placer mining and dealing with black sands as discussed in the article. If you have specific questions or need more details on any aspect, feel free to ask.

getting all the gold out of your concentrates (2024)

FAQs

What is the recovery of gold from concentrate? ›

Gold can be freed from these ores or concentrates by treating them with various oxidizing processes. The most common method is to roast gold-bearing minerals at temperatures of 450° to 750° C (840° to 1,380° F) to destroy the interfering sulfides.

What does hydrogen peroxide do to gold? ›

Although several authors have reported that the addition of small concentrations of hydrogen peroxide (0.35 mM) in the gold leaching medium have no effect on the cyanidation rate, Kameda reported in 1949 that larger concentrations (0.006 M) increase the gold dissolution rate, while a hydrogen peroxide concentration ...

How do you separate gold from other substances? ›

Most gold and silver are parted electrolytically after being recovered in the slimes left over from copper refining or as a metallic by-product of lead or zinc smelting. The bullion is cast into anodes, which are placed into an electrolytic cell and subjected to an electric current.

What is the gold recovery process? ›

Gold recovery comprises similar stages to the processing of most ores. First, the valuable minerals are separated from the gangue through concentration. The final concentrate is obtained by repeated processing and is smelted or leached in order to get a Dore bar.

How to process gold concentrates? ›

Gold concentrate is combined with a flux, such as borax or other materials of mixtures, in the crucible. The flux acts to decrease the melting temperature and viscosity of non-gold minerals in the concentrate so they are more easily separated from the gold during the cooling process.

What does toothpaste do to gold? ›

Toothpaste is abrasive and has a hardness of around 3/4 on the Mohs Scale of Hardness. Metals such as gold and silver are softer, so toothpaste can actually scratch damage your gold and silver jewellery. Not to mention, the chemicals in the flavour oils used in toothpaste are corrosive to metal.

What does rubbing alcohol do to gold? ›

Sterling Silver and Gold: For jewelry made of sterling silver or gold, you can use rubbing alcohol to clean and disinfect. Apply a small amount of rubbing alcohol to a soft cloth or cotton ball. Gently rub the jewelry, focusing on areas with tarnish or residue.

What solution dissolves gold? ›

The most useful and important vehicle for dissolving gold is aqua regia, (royal water), composed of two parts of hydrochloric (muriatic) acid, and one part of nitric (aquafortis).

What chemical is used to remove gold from ore? ›

A process called “Cyanidation”, or cyanide leaching, has been the dominant gold extraction technology since the 1970s. In this process sodium cyanide, in a dilute solution of ranging from 100 ppm to 500 ppm or 0.01% to 0.05% cyanide, is used to selectively dissolve gold from ore.

How to extract gold from ore at home? ›

The most common way to separate gold ore from rocks is through crushing, grinding and panning. First, the rock containing the ore must be crushed into a fine powder. This can be done through a crusher or by using a hammer to break the rock up. Then, the ore must be ground down further into a fine powder.

What does muriatic acid do to gold? ›

Muriatic acid, better known today as hydrochloric acid, is a simple, corrosive liquid with well-studied chemical properties. When gold is subjected to treatment with muriatic acid alone, nothing happens. But when \muriatic acid is combined with nitric acid to treat gold, the gold dissolves.

What does borax do to gold? ›

Why is borax used in melting gold? When used in a gold refining flux, borates keep recovery high and equipment degradation low. In gold metallurgy, borates are: Incorporated in refining flux formulations to dissolve metal oxides.

How to extract gold with milk? ›

The process involves grinding up discarded computer motherboards into a fine powder and then mixing it with the milk-derived aerogel. The aerogel acts as a sponge, absorbing the gold particles and leaving behind other materials.

Where to extract gold? ›

Collecting gold scrap can be a fun way to make some extra money. For this modern-day treasure hunt, your best bet is to look for gold jewelry in flea markets and thrift shops. If you're down for a chemistry experiment, you can also mine for gold in your old computers and other electronics.

What concentration of nitric acid for gold recovery? ›

If you are using nitric acid, add 30 ml to the container for each ounce of metal. If you are using MX3 or other nitric acid substitute for each ounce of metal. If you're using a nitric acid substitute: add 120 ml of hydrochloric (or muriatic) acid to the container, along with your substitute reagent.

Which is the most effective process for gold recovery? ›

The most cost-effective gold recovery solution for placer deposits is using a gravity concentration circuit. First, the material is screened to remove large rocks and boulders. Then a sluice or jig is used to recover the gold.

How do you recover gold from activated carbon? ›

For gold recovery, water and a cyanide such as calcium cyanide, sodium cyanide, or potassium cyanide, are added to ore or scraps to form a slurry. The gold will leach out and mix with the cyanide into a solution.

Can you get gold back from aqua regia? ›

The metallic gold can then be recovered from the reaction mixture by filtration or decantation. It has been found that this technique obviates the necessity for removal of the nitric acid from aqua regia solution of gold by destructive distillation.

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