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CORROSION 2004
March 28–April 1, 2004
New Orleans, Louisiana
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Killian Daniel Efird;
Killian Daniel Efird
Efird Corrosion International
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Jean L. Smith;
Jean L. Smith
Efird Corrosion International
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Nathan Davis;
Nathan Davis
Efird Corrosion International
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Sarah Blevins
Sarah Blevins
Efird Corrosion International
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Paper presented at the CORROSION 2004, New Orleans, Louisiana, March 2004.
Paper Number: NACE-04366
Published: March 28 2004
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Efird, Killian Daniel, Smith, Jean L., Davis, Nathan, and Sarah Blevins. "The Crude Oil Effect on Steel Corrosion: Wetability Preference and Brine Chemistry." Paper presented at the CORROSION 2004, New Orleans, Louisiana, March 2004.
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INTRODUCTION
ABSTRACT
The specific crude oil in crude oil/water production environments has a major effect on the corrosion of steel. The effect of the crude oil on steel corrosion in crude oil/water production is twofold. First, the crude oil changes the brine chemistry, affecting the corrosion rate and protectiveness of the corrosion product layer formed on the steel in much the same manner as synthetic corrosion inhibitors. This effect is predominant whenever a separated water phase is in contact with the steel, such as stratified pipe flow and the bottom of production separators, or when the crude oil and produced water are in a water external mixture. The effect is experimentally measured by corrosion tests in simulated produced water chemically equilibrated with the crude oil. Second, the crude oil affects the tendency of either water or crude oil to wet the surface influencing steel corrosion. This is termed wettability preference. This effect is predominant when the crude oil and produced water are mixed as in turbulent pipe flow and in production tubulars and is particularly significant for corrosion at low water contents. The corrosion rate break (CRB) water content experimentally measures the crude oil effect on wettability preference and steel corrosion in the crude oil/water mixture. Separately, each technique measures part of the total effect of crude oil on steel corrosion in crude oil-water production. Together the techniques define a much more complete picture of the effect of crude oil on steel corrosion behavior. Wettability preference and brine chemistry are two separate issues, and both must be evaluated to get a complete picture of the crude oil effect on steel corrosion.
In order to understand the effect of crude oil on steel corrosion, an understanding of the basic nature of crude oil is needed. This includes both the physical and chemical properties of crude oils and the various characterizations used for crude oils.
Chemical and Physical Characteristics of Crude Oil
Crude oil phase is a chemically complex liquid phase. It contains aliphatic and aromatic hydrocarbons, heterocyclic and metal organic compounds, high molecular weight organic compounds, and a broad assortment of nitrogen, sulfitr, and oxygen containing organic compounds. Crude oils are generally classified according to API gravity (inversely proportional to the crude oil density), sweet or sour, and asphaltenic or paraffinic (hydrocarbon characteristics). A so-called "heavy" crude oil has a low API gravity (<20), a "medium" crude oil has an intermediate API gravity (20 to 34), while a "light" crude oil has a high API gravity (>34). These ranges are not absolutely defined, but serve as a general reference. Another way of classifying crude oils is based on the nature of the organic compounds that make up the crude oil, specifically the proportions of paraffins, aromatic compounds, and naphthenic compounds, as shown in Figure 1. ~
Keywords:
Subsurface Corrosion, corrosion rate, Pipeline Corrosion, well integrity, wettability preference, organic compound, flowline corrosion, riser corrosion, water content, water corrosion rate
Subjects:
Pipelines, Flowlines and Risers, Materials and corrosion, Well Integrity, Subsurface corrosion (tubing, casing, completion equipment, conductor)
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2004. NACE International
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