The Crude Oil Effect on Steel Corrosion: Wetability Preference and Brine Chemistry (2024)

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CORROSION 2004

March 28–April 1, 2004

New Orleans, Louisiana

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Killian Daniel Efird;

Killian Daniel Efird

Efird Corrosion International

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Jean L. Smith;

Jean L. Smith

Efird Corrosion International

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Sarah Blevins

Sarah Blevins

Efird Corrosion International

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Paper presented at the CORROSION 2004, New Orleans, Louisiana, March 2004.

Paper Number: NACE-04366

Published: March 28 2004

Citation

Efird, Killian Daniel, Smith, Jean L., Davis, Nathan, and Sarah Blevins. "The Crude Oil Effect on Steel Corrosion: Wetability Preference and Brine Chemistry." Paper presented at the CORROSION 2004, New Orleans, Louisiana, March 2004.

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INTRODUCTION

ABSTRACT

The specific crude oil in crude oil/water production environments has a major effect on the corrosion of steel. The effect of the crude oil on steel corrosion in crude oil/water production is twofold. First, the crude oil changes the brine chemistry, affecting the corrosion rate and protectiveness of the corrosion product layer formed on the steel in much the same manner as synthetic corrosion inhibitors. This effect is predominant whenever a separated water phase is in contact with the steel, such as stratified pipe flow and the bottom of production separators, or when the crude oil and produced water are in a water external mixture. The effect is experimentally measured by corrosion tests in simulated produced water chemically equilibrated with the crude oil. Second, the crude oil affects the tendency of either water or crude oil to wet the surface influencing steel corrosion. This is termed wettability preference. This effect is predominant when the crude oil and produced water are mixed as in turbulent pipe flow and in production tubulars and is particularly significant for corrosion at low water contents. The corrosion rate break (CRB) water content experimentally measures the crude oil effect on wettability preference and steel corrosion in the crude oil/water mixture. Separately, each technique measures part of the total effect of crude oil on steel corrosion in crude oil-water production. Together the techniques define a much more complete picture of the effect of crude oil on steel corrosion behavior. Wettability preference and brine chemistry are two separate issues, and both must be evaluated to get a complete picture of the crude oil effect on steel corrosion.

In order to understand the effect of crude oil on steel corrosion, an understanding of the basic nature of crude oil is needed. This includes both the physical and chemical properties of crude oils and the various characterizations used for crude oils.

Chemical and Physical Characteristics of Crude Oil

Crude oil phase is a chemically complex liquid phase. It contains aliphatic and aromatic hydrocarbons, heterocyclic and metal organic compounds, high molecular weight organic compounds, and a broad assortment of nitrogen, sulfitr, and oxygen containing organic compounds. Crude oils are generally classified according to API gravity (inversely proportional to the crude oil density), sweet or sour, and asphaltenic or paraffinic (hydrocarbon characteristics). A so-called "heavy" crude oil has a low API gravity (<20), a "medium" crude oil has an intermediate API gravity (20 to 34), while a "light" crude oil has a high API gravity (>34). These ranges are not absolutely defined, but serve as a general reference. Another way of classifying crude oils is based on the nature of the organic compounds that make up the crude oil, specifically the proportions of paraffins, aromatic compounds, and naphthenic compounds, as shown in Figure 1. ~

Keywords:

Subsurface Corrosion, corrosion rate, Pipeline Corrosion, well integrity, wettability preference, organic compound, flowline corrosion, riser corrosion, water content, water corrosion rate

Subjects:

Pipelines, Flowlines and Risers, Materials and corrosion, Well Integrity, Subsurface corrosion (tubing, casing, completion equipment, conductor)

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The Crude Oil Effect on Steel Corrosion: Wetability Preference and Brine Chemistry (2024)

FAQs

Can crude oil cause corrosion? ›

Crude oil, as a mixture of all sorts of hydrocarbons, is not corrosive. However, there are some impurities and components often found in crude oil that could cause corrosion in pipelines, vessels and refinery equipment such as atmospheric columns, overhead lines, exchangers and condensers.

Why is it important to remove the metals from crude oil? ›

The avoidance of adding metals and the assistance in removing other metals from the crude system aids in the reduction or elimination of downstream fouling and petroleum catalyst poisoning.

Which type of corrosion will occur when a piece of carbon steel is exposed to salt water? ›

Inasmuch as seawater is highly conductive, galvanic corrosion will occur unless care is taken to prevent the use of improper metallurgy. Crevice corrosion will be common in susceptible areas due to growth of anaerobic bacteria shielded from treatments.

What is the centrifuge method for water and sediment in crude oil? ›

The centrifuge method for water in crude oil, known as BS & W (Basic Sediment & Water), involves spinning a specified amount of sample for a specified time in a heated centrifuge until all the water and sediment settle in the bottom of the centrifuge tube.

Does steel corrode in oil? ›

Currently, carbon steels or low-alloy carbon steels are still cost-effective materials for manufacturing oil tubes and pipelines although they are very susceptible to corrosion in the aggressive environments of oil and gas production and transportation (Ref 1, 2).

Does oil slow down corrosion? ›

Oil not only lubricates metal parts but also allows them to move with less friction. Oiling forms a protective layer on the metal to prevent it from rust. The principle here is pretty simple; with a coating of oil, moisture is unable to react with the iron in the metal and cause rust.

How do you separate metal from oil? ›

Filtration: The process of separating solid particles from a liquid by passing through a filter or pores of filter paper is called filtration. Using an appropriate filter we can separate small pieces of metal from the engine oil of the car.

Why do you put oil on metal? ›

Oil just not only lubricates metal parts. But it also makes them move more smoothly. Oiling can safeguard from rust by generating a protective layer on the metal. The concept is simple: when a metal is coated with oil, moisture cannot react with the iron in the metal and cause rust.

Why is oil applied on the surface of a metal? ›

Among them, oiling is one of the best and conventional methods used to protect the metal from rust. As oil and water do not mix with each other, oiling forms a protective coating for the metal and hence prevent it from rusting. Oil can penetrate the oxide-water on the metal and stabilize it.

Why does salt water corrode steel? ›

Corrosion on Metal

Salt water corrosion of metals happens faster than freshwater because of the increase presence of dissolved ions. These ions allow electrons to move faster on the metal, speeding up the formation of rust. The metal doesn't have to be submerged in salt water for this to happen.

Does salt affect corrosion rate? ›

Because salt is a powerful electrolyte, it contains a large number of dissociated ions, which greatly accelerates corrosion in salt water. Salt, or more particularly, salt solution, can hasten the rusting process by acting as an electrolyte, allowing the metal (iron) to lose electrons more quickly.

Why steel corrodes faster in saltwater and acidic environment? ›

Salt water is an electrolyte which conducts ions, speeding up rusting. No rust. Calcium chloride dries out the air. Salt solution acts as an electrolyte (any substance containing free ions that allows the substance to conduct electricity) allowing iron to lose electrons more easily and so speeds up the rusting process.

Which method is used to separate crude oil from water? ›

Decantation is employed to separate immiscible liquids that have two different densities. For example, when a mixture of oil and water is present in a container, two distinct layers in the liquid mixture is formed. It is clearly visible that the oil layer is floating on top of the water layer.

What is the sedimentation of crude oil? ›

Sedimentation is the sorption of oil to suspended sediments that eventually settle out of the water column and accumulate on the seafloor.

How do you filter crude oil from water? ›

If you have a sump that you can pour oily water into, you should be able to absorb the oil floating on the water with oil-only mats, socks or pillows. Oil-only products are also a great solution if you need to remove oil from pond water.

What problems are caused by crude oil? ›

Specifically, oil and gas exploration and development causes disruption of migratory pathways, degradation of important animal habitats, and oil spills—which can be devastating to the animals and humans who depend on these ecosystems.

Is crude oil corrosive to skin? ›

Skin contact with crude oil that lasts a long time can cause skin reddening, swelling, and burning. The skin effects can get worse if the skin is exposed to the sun. Skin contact can also make you more likely to develop a rash or skin infection. Light crude oil may also be irritating if it contacts your eyes.

Is fuel oil corrosive? ›

a) the fuel oil always contains impurities, though in variable proportions according to its origin. b) partial and total corrosions are produced in the exhaust valves of the engines, more corrosion occurs when the quantity of vanadium and sodium in present the fuel oil is higher.

What does crude oil turn into in rust? ›

Crude Oil is a new resource which can be commonly obtained from Pump Jacks or oil Barrels. It can be refined via the Small Oil Refinery into Low Grade Fuel. You can also sell 6 crude oil for 1 scrap at bandit camp.

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